July 15, 2020
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Article

Effect of scCO2-brine mixture on injectivity and storage capacity in rock samples of naturally fractured carbonate formations

Publicated to: Journal of Natural Gas Science and Engineering. 81 (103452): 103452- - 2020-09-01 81(103452), DOI: 10.1016/j.jngse.2020.103452

Authors:

Valle, LM; Grima, C; Rodríguez, R; Llopis, C
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Affiliations

Univ Politecn Madrid, Madrid, Spain - Author
Univ Politecn Valencia, Valencia, Spain - Author
Universidad Politécnica de Madrid - Author
Universitat Politècnica de València - Author
Upm - Author
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Abstract

© 2020 Elsevier B.V. The presence of natural fractures in the formation and its degree of heterogeneity condition the injection of CO2 into the aquifer as they affect the migration processes and its storage capacity. In ATAP experimental facility the petrophysical behavior of two carbonate formations was studied, with different proportions of limestone, dolomite, quartz and anhydrite and fissures sealed mainly by potassium aluminosilicates and iron sulphides. Actual storage conditions (135/141 bar and 44/46 ᵒC) corresponding to a depth of around 1500 m and continuous injection at a constant flow rate of 1 cc/min of 10% and 15% of HCl, HCl/Acetic (CH3COOH) 10%/10% and scCO2 (supercritical CO2)/brine 50%/50%, was applied to the brine saturated rock samples (coreflooding). Considering laminar flow through the fractures, the flow injected is proportional to the pressure drop according to the “cubic law” that takes into account the width and length of the fractures. This is used to evaluate the injectivity of the storage. The variations in the pressure drop are due to the dragging of detached fines in the dissolution of the carbonates of the filled fissures that can cause their opening or blocking. The efficacy of pure scCO2 enriched brine injection was determined to dissolve the carbonates of the store formation compared to other methods such as the injection of acids used in the oil industry for the stimulation of producing wells. Scanning Electron Microscope (SEM) studies of the injection surfaces and Computerized Tomography (CT) analysis of the samples before and after injection of the acid mixtures have been performed. The dissolution facilitates the injectivity and increases the capacity favoring the tightness of the storage by the phenomenon of controlled dissolution-precipitation of the carbonates.
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Keywords

2-phase flowCarbonate dissolutionDeep saline aquifersDissolution kineticsEffective porosityFines migrationFormation permeabilityFractal analysisFractured acidizingGeological storageMinerals relevantPotential co2-injection sitesShale gasSupercritical co2 injection

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal Journal of Natural Gas Science and Engineering due to its progression and the good impact it has achieved in recent years, according to the agency WoS (JCR), it has become a reference in its field. In the year of publication of the work, 2020, it was in position 32/143, thus managing to position itself as a Q1 (Primer Cuartil), in the category Engineering, Chemical.

Independientemente del impacto esperado determinado por el canal de difusión, es importante destacar el impacto real observado de la propia aportación.

Según las diferentes agencias de indexación, el número de citas acumuladas por esta publicación hasta la fecha 2026-04-24:

  • Google Scholar: 12
  • WoS: 11
  • Scopus: 11
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Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2026-04-24:

  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 18 (PlumX).

It is essential to present evidence supporting full alignment with institutional principles and guidelines on Open Science and the Conservation and Dissemination of Intellectual Heritage. A clear example of this is:

  • The work has been submitted to a journal whose editorial policy allows open Open Access publication.
  • Assignment of a Handle/URN as an identifier within the deposit in the Institutional Repository: https://oa.upm.es/85867/

As a result of the publication of the work in the institutional repository, statistical usage data has been obtained that reflects its impact. In terms of dissemination, we can state that, as of

  • Views: 104
  • Downloads: 102
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Leadership analysis of institutional authors

There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (VALLE FALCONES, LAURA MARIA) .

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